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Solution For The compression factor (compressibility factor) for one mole of a Van der Waals' gas at 0∘C and 100 atmosphere pressure is found to be 0.5 . Assuming that the volume of a gas molecule is
The compression factor (compressibility factor) for one mole of a Van der Waals' gas at 0∘C and 100 atmosphere pressure is found to be 0.5 . Assuming that the volume of a gas molecule is negligible, calculate the Van der Waals' constant 'a', [JEE 2001] ns. 1.256 atm L2 mol−2 Z=1−VmRTa​Z=RTPVm​⇒Vm=PRTZ​Z=1−(RT)2a​×ZP​0.5=1−(273×0.0821)2×.5a×100​a=1.256 atm L2 mol−2​
Video solution 1: The compression factor (compressibility factor) for one mole of a Van der Waals' gas at 0∘C and 100 atmosphere pressure is found to be 0.5 . Assuming that the volume of a gas molecule is negligible, calculate the Van der Waals' constant 'a', [JEE 2001] ns. 1.256 atm L2 mol−2 Z=1−VmRTa​Z=RTPVm​⇒Vm=PRTZ​Z=1−(RT)2a​×ZP​0.5=1−(273×0.0821)2×.5a×100​a=1.256 atm L2 mol−2​

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