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Solution For The compression factor (compressibility factor) for one mole of a Van der Waals' gas at 0∘C and 100 atmosphere pressure is found to be 0.5 . Assuming that the volume of a gas molecule is
The compression factor (compressibility factor) for one mole of a Van der Waals' gas at 0∘C and 100 atmosphere pressure is found to be 0.5 . Assuming that the volume of a gas molecule is negligible, calculate the Van der Waals' constant 'a',
[JEE 2001]
ns. 1.256 atm L2 mol−2
Z=1−VmRTaZ=RTPVm⇒Vm=PRTZZ=1−(RT)2a×ZP0.5=1−(273×0.0821)2×.5a×100a=1.256 atm L2 mol−2
Video solution 1: The compression factor (compressibility factor) for one mole of a Van der Waals' gas at 0∘C and 100 atmosphere pressure is found to be 0.5 . Assuming that the volume of a gas molecule is negligible, calculate the Van der Waals' constant 'a',
[JEE 2001]
ns. 1.256 atm L2 mol−2
Z=1−VmRTaZ=RTPVm⇒Vm=PRTZZ=1−(RT)2a×ZP0.5=1−(273×0.0821)2×.5a×100a=1.256 atm L2 mol−2
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